Aquabis(4-methylbenzoato)-κO;κ2 O,O′-bis(pyridine-κN)nickel(II)
نویسندگان
چکیده
In the title mononuclear complex, [Ni(C(8)H(7)O(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral arrangement, coordinated by three carboxylate O atoms from one bidentate 4-methyl-benzoate ligand and one monodentate 4-methyl-benzoate ligand, two N atoms from pyridine ligands, axially positioned, and a water mol-ecule. The equatorially positioned water mol-ecule and uncoordinated carb-oxylate O atom form an intra-molecular hydrogen bond. An inter-molecular O-H⋯O hydrogen bond between the coordinated water mol-ecule and carboxylate O atom of the 4-methyl-benzoate ligand forms infinite chains along the b axis. These chains are connected by C-H⋯π inter-actions.
منابع مشابه
Aquabis(1H-imidazole-κN 3)bis(4-methylbenzoato)-κO;κO,O′-nickel(II)
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